From Table 3, we can obtain that the theoretical analysis and experiment have good
agreement for elastic modules of three - phase composite made of polyester matrix, glass
fibers and titanium oxide particles. This conclusion allows us to apply the algorithm and
formulas proposed in this research for estimating the elastic modules and other structure
and material problems using three - phase composite.
The authors would like to thank the Laboratory of Shipbuilding Technology Institute, Nha Trang University for their assistance on experiments.
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Vietnam Journal of Mechanics, VAST, Vol. 33, No. 2 (2011), pp. 105 – 112
EXPERIMENTAL STUDY ON MECHANICAL
PROPERTIES FOR A THREE - PHASE POLYMER
COMPOSITE REINFORCED BY GLASS FIBERS AND
TITANIUM OXIDE PARTICLES
Nguyen Dinh Duc1, Dinh Khac Minh2
1University of Engineering and Technology
2Shipbuilding Science and Technology Institute
Abstract. Nowadays, composite materials are applied in many fields. The physico -
mechanical properties of the material can be improved by adding reinforced fibers and
particles. Many scientists pay attention to the calculation for elastic modules of three -
phase composite materials. This report presents the experimental results for some elastic
modules of three - phase polymer composite reinforced with glass fibers and titanium
oxide particles of different volume ratios. A comparison between experimental and the-
oretical results shows good agreement.
Key words: Three - phase composite (polyester, glass fiber, titanium oxide), elastic
modulus, experimental.
1. INTRODUCTION
Composite material consists of two or more component materials to obtain a new
material with better properties. The components are matrix material and filled materials
(reinforced or additive). The function of matrix material is to unite the components, assure
the resistance to heat and physicochemical loads, while the filled components are used to
improve the mechanical properties (stiffness and strength) of the composite [5, 6, 7, 10].
The reinforced components used usually are fibers and particles. Fibers can increase
the stiffness, while particles can decrease the fracture, plastic strain and improve the water
and gas proof ability of the composite. Thus, the addition of fibers and particles can
make composite become more perfect, to satisfy more and more requirements of modern
technology.
Having advantages such as: light weight, resistance to heat and environmental loads,
composite materials are widely applied in many fields: from industry, construction, ma-
chine - building, transportation to aerospace engineering and medical engineering. In Viet-
nam, within the past ten years, many researches and applications for composite have been
done, especially for polymer composites. The properties of polymer composites is indicated
in [5, 6, 9]. In ship building industry, guard ship, passenger ship, fishing vessel of small and
medium sizes are mainly made of composite materials. To improve the water - proof, fire
106 Nguyen Dinh Duc, Dinh Khac Minh
- proof, corrosion - proof and crack resistant properties of the material, particles often be
added to the matrix besides fibers. This leads to the appearance of three - phase composite
which having three phases: polymer matrix, reinforced fibers and particles. To deal with
the structural problems, we need to know the mechanical behavior of the material, which
means firstly determining the elastic modules of the composite (Fig. 1).
Fig. 1. Model of three - phase composite with reinforced fiber and particle
2. DETERMINE THE ELASTIC MODULES OF THREE - PHASE
COMPOSITE
There are two main methods for determining the elastic modules of three - phase
composite material: experimental and analytical methods. The advantage of experimental
method is that it can provide the exact result for the material’s modules. However, since
three - phase composite is a multi - component material, the experiment can not illustrate
the effect that the component phases have on the overall mechanical properties of the
material. The analytical method often uses a mechanical model of a three-phase composite
material reinforced with fibers (normally in cylindrical shape) and particles (in spherical
shape) to calculate the material’s elastic modules. It has a principal advantage: the modules
are explicitly determined from the properties and aspect ratios of the component phase.
When these factors are changed, new composite is obtained and their physicomechanical
properties can be predicted, thus this method provides the foundation for optimal design
of new material and structure.
Another method is the inductive method, in which the predicted formulas for the
elastic modules are derived based on a large number of experiments. Such formulas are
often suggested by the scientists in experimental physics. But with the appearance of the
third phase, the experiments and the prediction for the variation of the elastic modules
from the component phases’ parameters become very complex. So far we have only seen
publications [10] using this method for two - phase composites (matrix and reinforced
particles).
In our previous reports, the elastic modules of three - phase composites are estimated
using two theoretical models of the two - phase composite consecutively: nDm = Om+nD
Experimental study on mechanical properties for a three - phase polymer composite... 107
[3, 4, 12]. This paper considers three - phase composite reinforced with particles and
unidirectional fibers, so the problem’s model will be: 1Dm = Om +1D.
The researches on determining the elastic modules for composite material with re-
inforced particles are reported in [1, 2, 10, 11, 12]. In our papers [11, 12], the interaction
between matrix and particles is taken into account. Firstly, the modules of the effective
matrix Om which called "effective modules" are calculated. In this step, the effective
matrix consists of the original matrix and particles, it is considered to be homogeneous,
isotropic and have two elastic modules. The next step is estimating the elastic modules for
a composite material consists of the effective matrix and unidirectional reinforced fibers.
Thus, the result for the three - phase composite problem depends much on the
models for the two - phase composite problem and it can have different accuracy for
different composites.
For composite reinforced with particles, several methods for determining elastic
modules have been proposed [1, 2, 10, 11, 12]. In this research, we chose the method which
takes into account the interaction between matrix and particle [2, 12].
There are also researches on determining the elastic modules for composite reinforced
by unidirectional fibers [1, 7, 8, 11]. This type of material is often considered orthotropic
with 5 elastic modules [1, 7]. The most modern reports with two independent approaches by
Pobedrya B.E. [8] and Vanin G.A. [11] have calculated the sixth modulus of this material,
and their results show good agreement to each other.
Assume that all the component phases (matrix, fiber and particle) are homogeneous
and isotropic, we will use Em, νm, Ea, νa, Ec, νc to denote Young modulus and Poisson ratio
for matrix, fiber and particle, respectively. According to [2], we can obtain the modules
for the effective composite as below:
G¯ = Gm
1− ξc (7− 5νm)H
1 + ξc (8− 10νm)H
(1)
K¯ = Km
1 + 4ξcGmL (3Km)
−1
1− 4ξcGmL (3Km)
−1
(2)
here,
L =
Kc −Km
Kc +
4Gm
3
, H =
Gm/Gc − 1
8− 10νm + (7− 5νm)
Gm
Gc
. (3)
E¯, ν¯ can be calculate from (G¯, K¯) as below
E¯ =
9K¯G¯
3K¯ + G¯
, ν¯ =
3K¯ − 2G¯
6K¯ − 2G¯
(4)
The modules for three - phase composite reinforced with unidirectional fiber are
chosen to be calculated using Vanin’s formulas [11]:
108 Nguyen Dinh Duc, Dinh Khac Minh
E11 = ξaEa + (1− ξa) E¯ +
8G¯ξa (1− ξa) (νa − ν¯)
2− ξa + x¯ξa + (1− ξa) (xa − 1)
G¯
Ga
,
E22 =
ν2
21
E11
+
1
8G¯
2 (1− ξa) (χ− 1) + (χa − 1)(χ− 1 + 2ξa)
G¯
Ga
2− ξa + χξa + (1− ξa)(χa − 1)
G¯
Ga
+
+2
χ (1− ξa) + (1 + ξaχ)
G¯
Ga
χ+ ξa + (1− ξa)
G¯
Ga
−1
,
G12 = G¯
1 + ξa + (1− ξa)
G¯
Ga
1− ξa + (1 + ξa)
G¯
Ga
, G23 = G¯
χ+ ξa + (1− ξa)
G¯
Ga
(1− ξa)χ+ (1 + χξa)
G¯
Ga
,
ν23
E22
= −
ν2
21
E11
+
1
8G¯
2
(1− ξa) x¯ + (1 + ξax¯)
G¯
Ga
x¯+ ξa + (1− ξa)
G¯
Ga
−
−
2 (1− ξa) (x¯− 1) + (xa − 1) (x¯− 1 + 2ξa)
G¯
Ga
2− ξa + x¯ξa + (1− ξa) (xa − 1)
G¯
Ga
,
ν21 = ν¯ −
(χ+ 1) (ν¯ − νa) ξa
2− ξa + χξa + (1− ξa) (χa − 1)
G¯
Ga
.
(5)
in which x¯ = 3− 4ν¯.
One of the goals of this research is to do the experiments to verify the results for the
modules E11, E22, G12 of three - phase composite materials calculated using the formulas
(5) above.
3. EXPERIMENT AND RESULT
To verify Young modules for three - phase composite, we tested the samples made
of polyester AKAVINA (made in Vietnam), fibers (made in Korea) and titanium oxide
(made in Australia) with the properties as in Table 1.
The experiments were done on HOUNSFEILD H50K-S tester (Fig. 2) using BS EN
ISO 527-1: 1997 method. Room’s temperature was (20±50C), humidity was 65%±20%.
The samples were made according to Vietnamese standard code: TCVN 6282:2008 [13].
The dimension of the samples is given in Fig. 3. The experiments were done at the Labo-
ratory of Shipbuilding Technology Institute, Nha Trang University.
Experimental study on mechanical properties for a three - phase polymer composite... 109
Table 1. Properties of component phases for the three - phase composite
Component phase Young modulus E Poisson ratio ν
Matrix polyester AKAVINA (Vietnam) 1,43 Gpa 0.345
Glass fiber (Korea) 22 Gpa 0.24
Titanium oxide TiO2 (Australia) 5,58 Gpa 0.20
Fig. 2. HOUNSFEILD H50K-S Tester
Fig. 3. Dimension of three - phase composite sample
Totally more than 60 samples were tested for 8 different cases of fibers and particle’s
volume ratios (as in the first column of Table 2). Tensile test was done for estimating E11,
E22 and in 45 degree direction for estimating E45 and G12. The experiments’ results is
given in Table 2.
According to the tests’ results, fiber has much effect on improving Young modulus,
while particle has much effect on shear modulus.
110 Nguyen Dinh Duc, Dinh Khac Minh
Table 2. Experiment results for three - phase composite’s elastic modules
Elastic Modulus
Composite E45 E1 E2 G12
20%TiO2 + 15%W800 + 65% polyester
3012.36 4548.25 2750.58 742.07
2996 4673.56 2678.5 720.138
2977.7 4695.67 2670.26 700.504
2879.5 4825.34 2740.79 700.18
20%TiO2 + 20%W800 + 60% polyester
3768.89 6208.64 2828.56 719.518
3752.2 6330.28 2931.42 715.799
3527.23 6347.5 2815.96 713.146
3340.08 6191.18 2923.98 712.51
20%TiO2 + 25%W800 + 55% polyester
3725.65 7270.8 3018.02 701.868
4001.73 6981 3158.63 702.952
3791.82 6959.8 3377.35 705.731
3582.3 6911 3045.76 701.31
3889.3 6956 3072.91 702.432
20%TiO2 + 30%W800 + 50% polyester
4330 7658.5 3230.54 677.701
4275 7580.4 3267.62 697.542
4106.81 7604 3254.59 700.201
30%TiO2 + 15%W800 + 55% polyester
2046.11 4725 2939.3 818.577
2467.39 4774 2932.81 800.125
2614.2 5073 3033.59 844.859
2244.17 5231 2997.34 801.6411
30%TiO2 + 20%W800 + 50% polyester
4025 6341 3278.59 807.049
3819.55 6423 3146.34 801.252
3738.52 6582.5 3178.75 803.382
30%TiO2 + 25%W800 + 45% polyester
3661.27 6875 3425.62 799.966
3992.65 6465 3462.25 805.524
3623.84 7012 3659.15 791.349
3707.86 6609 3547.13 786.753
30%TiO2 + 30%W800 + 40% polyester
4342.58 8230 3655.53 768.72
4229.44 8308 3708.33 761.511
4090 8092 3602.52 775.503
4111.5 8792 3670.48 801.844
The comparison between experimental results (average values from Table 2) with
theoretical result ( formulas (5)) is shown in Table 3.
4. CONCLUSION
From Table 3, we can obtain that the theoretical analysis and experiment have good
agreement for elastic modules of three - phase composite made of polyester matrix, glass
fibers and titanium oxide particles. This conclusion allows us to apply the algorithm and
formulas proposed in this research for estimating the elastic modules and other structure
and material problems using three - phase composite.
The authors would like to thank the Laboratory of Shipbuilding Technology Insti-
tute, Nha Trang University for their assistance on experiments.
Experimental study on mechanical properties for a three - phase polymer composite... 111
Table 3. Comparison between experiment and analysis
Composite E1 E2 G12
20%TiO2 + 15%W800 + 65% polyester
Experimental 4685.70 2709.95 715.72
Theoretical 4787.5 2791.0 673.8
Error 2.1% 2.9% 6.2%
20%TiO2 + 20%W800 + 60% polyester
Experimental 6269.4 2874.98 715.24
Theoretical 5781.7 2996.7 666.9
Error 8.4% 4.1% 7.3%
20%TiO2 + 25%W800 + 55% polyester
Experimental 7015.72 3152.55 708.65
Theoretical 6778.4 3221.7 659.3
Error 3.5% 2.2% 7.5%
20%TiO2 + 30%W800 + 50% polyester
Experimental 7614.3 3250.91 691.8
Theoretical 7777.5 3468.9 650.7
Error 2.1% 6.7% 6.3%
30%TiO2 + 15%W800 + 55% polyester
Experimental 4950.75 2975.76 816.30
Theoretical 4980.5 3091.6 766.5
Error 0.6% 3.7% 6.5%
30%TiO2 + 20%W800 + 50% polyester
Experimental 6348.6 3201.22 803.9
Theoretical 5962.1 3310.4 757.7
Error 6.5% 3.4% 6.1%
30%TiO2 + 25%W800 + 45% polyester
Experimental 6717.75 3523.54 795.90
Theoretical 6946.3 3549.1 747.9
Error 3.4% 0.7% 6.4%
30%TiO2 + 30%W800 + 40% polyester
Experimental 8355.5 3659.22 776.89
Theoretical 7933.1 3810.6 737.0
Error 5.3% 4.1% 5.4%
The results of researching presented in the paper have been performed according
to scientific research project of Vietnam National University, Hanoi (VNU, Hanoi), coded
QGTĐ.09.01.
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Received September 20, 2010
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