The MnAC samples were successfully prepared via magnetic stirring and ultrasonic stirring
methods. The resulted samples are amorphous structure with 32~42% MnO2 loading. The
magnetic stirring prepared sample has spherical particles while ultrasonic stirring sample has
mixed spherical and rod-like particle. The introducing of manganese oxide resulted in a drop in
specific surface area and pore volume compared to activated carbon sample. Electrochemical
investigates show that at low scan rate or low current density, MnAC-U have better performance
while at high scan rate or high current density, MnAC-M is superior to MnAC-U.
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Vietnam Journal of Science and Technology 56 (5) (2018) 582-593
DOI: 10.15625/2525-2518/56/5/10997
SYNTHESIS, CHARACTERIZATION AND ELECTROCHEMICAL
PERFORMANCE OF ACTIVATED CARBON SUPPORTED MnO2
FOR ELECTROCHEMICAL CAPACITOR
Luong Thi Thu Thuy, Le Van Khu, Nguyen Thi Kim Lien
Faculty of Chemistry, Hanoi National University of Education, 136 Xuan Thuy St.,
Cau Giay Dist., Ha Noi
*
Email: thuyltt@hnue.edu.vn
Received: 20 December 2017; Accepted for publication: 1 September 2018
Abstract. MnO2 was synthesized by adding activated carbon into KMnO4 solution and stirred in
a magnetic or ultrasonic stirrer. The obtained MnAC samples were characterized by means of
XRD, TGA, TPR-H2, SEM and BET. All samples are amorphous and have porous structure.
MnAC-M prepared by magnetic stirring have higher manganese content, earlier reduction
temperature, smoother surface area while MnAC-U prepared by ultrasonic stirring have larger
specific surface area and pore volume. Electrochemical studies revealed that at low scan rate the
specific capacitance of MnAC-U is larger than that of MnAC-M, while at high scan rate the
specific capacitance of MnAC-M is higher. All the results indicated that the differences of the
performances of MnAC electrodes from the different stirring methods arose from the different
microstructure characteristic and the metal oxide loading of MnAC samples.
Keywords: electrochemical capacitor, activated carbon, manganese oxide, magnetic stirring,
ultrasonic stirring.
Classification numbers: 2.4.4; 2.8.2
1. INTRODUCTION
Along with the development of sustainable energy which has intermitten nature, the need of
energy storage system has grown dramatically in recent years. Due to the high power density,
excellent reversibility and long cycle life, electrochemical capacitors have been attracting
worldwide attention. Based on the charge storage mechanisms, electrochemical capacitor can be
classified into two groups: i) Electric double layer capacitor (EDLC) that uses high surface area
materials as electrode and store charge at the interface and ii) Pseudo-capacitors that uses fast
and reversible reaction of transition metal oxides or conducting polymers for charge storage [1].
MnO2 is one of the most inexpensive, abundant and non-toxic cathodic materials with high
theoretical capacitance (1370 F g
-1
, Mn
4+
→ Mn3+ [2]). However, the low reversibility of
oxidation/reduction and the low conductivity of MnO2 (10
-5
- 10
-6
S cm
-1
[3]) reducing its
capacitance, which in turn limits its commercialization. Introducing MnO2 onto activated carbon
Synthesis, characterization and electrochemical performance
583
surface has been proved to greatly increase the conductivity as well as the specific capacitance
of the active material [4].
Chemical precipitation method is among the simplest techniques for synthesizing MnO2
nanoparticles. However, in MnO2/activated carbon case, MnO2 tend to aggregate into bigger
particles which in turn decrease the active sites and cause the blockage of the activated carbon
pores [5]. Hence, stirring is essential to prevent the particle agglomeration/aggregation and is
one of the prime issues to increase the performance of MnO2/activated carbon materials. Particle
size, specific surface area, and pore volume can vary substantially when using different stirring
methods. This work presents the synthesis and characterization of MnAC materials and the
effect of stirring methods, namely magnetic and ultrasonic stirring, to electrochemical property
of the as-prepared materials based on cyclic voltammetry (CV) and galvanostatic
charge/discharge tests.
2. MATERIALS AND METHODS
2.1. Materials
2.1.1. Synthesis of MnAC materials
Rice husk base activated carbon (RH-AC) was prepared using the mixture of NaOH and
KOH as activating agents and was activated at 800
o
C. Some features of RH-AC including:
specific surface area 2990 m
2
g
-1
, micropore surface area 2747 m
2
g
-1
, external surface area 243
m
2
g
-1
, micropore volume 1.4316 cm
3
g
-1
, total pore volume 1.8084 cm
3
g
-1
.
All chemicals were of analytical grade and used without further purification. RH-AC was
dried at 120
o
C in 5 hours and dry ball milled at 500 rpm in a Fritsch Pulverisette 7 ball mill for 15
min. Thereafter, 1.0 g milled RH-AC was dispersed into 50 mL 0.2 M KMnO4 solution and
stirred in a magnetic or ultrasonic stirrer for 60 min. The obtained precipitates were filtered and
washed several times with distilled water and then dried at 120
o
C in 24 hours. MnAC materials
were achieved through the following reaction: 4
4MnO + 3C + H2O → 4MnO2 +
2
3CO +
2
3HCO [6]. The resulted samples were labeled as MnAC-M and MnAC-U, in which M stands
for magnetic stirring and U stands for ultrasonic stirring.
2.1.2. Electrode preparation
The fabrication of working electrodes was carried out by mixing MnAC materials,
polytetrafluoroethylene (PTFE) and graphite with mass ratio of 70:15:15 and dispersed in
ethanol. The resulting mixture was coated onto nickel foam substrate (1 cm
2
) with a doctor
blade, dried at 120
o
C in 10 h, and pressed under 20 MPa.
2.2. Analytical methods
X-ray diffraction (XRD) patterns were obtained on a D8 Advance (Bruker) with Cu Kα
radiation as the X-ray source. Thermogravimetric analysis (TGA) was collected on a
thermogravimetric analyzer DTG-60H (Shimadzu) with a temperature ramp of 10
o
C min
-1
.
Hydrogen temperature-programed reduction (TPR-H2) experiments were performed using an
AutoChem II instrument (Micromeritics) in the temperature range 50 ~ 600
o
C with a heating
rate of 10
o
C min
-1
. The morphology of the samples was observed using a scanning electron
Luong Thi Thu Thuy, Le Van Khu, Nguyen Thi Kim Lien
584
microscope JSM-6390 (Jeol). The textural properties were investigated using physical
adsorption of nitrogen at 77 K on a TriStar 3000 instrument (Micromeritics); the samples were
degassed at 220
o
C for 7 hours prior to all measurements.
Electrochemical behavior was investigated using an Autolab PGSTAT 302N instrument in
6M KOH electrolyte solution. The electrochemical cell was a three electrode system: the as-
prepared electrode as working electrode, a platinum wire as counter electrode and the saturated
calomel as reference electrode. Cyclic voltammograms (CV) were conducted between -1.1 ~ -
0.1 V at scan rates of 5, 10, 30, and 50 mV s
-1
. Galvanostatic charge/discharge measurements
were recorded at current densities of 0.5, 1.0, 2.0, and 3.0 A g
-1
within the same voltage range of
CV measurements.
3. RESULTS AND DISCUSSION
3.1. Characterization
3.1.1. XRD analysis
The XRD patterns of RH-AC, MnAC-M and MnAC-U samples are shown in Fig. 1. There
are no diffraction peaks implying an amorphous structure of the samples. This result matches
well with literature, that synthesis temperature below 400
o
C would form amorphous MnO2 [7].
2-Theta Scale
20 30 40 50 60 70 80
L
in
(
C
p
s
)
MnAC-M
MnAC-U
RH-AC
Figure 1. XRD patterns of RH-AC, MnAC-M, and MnAC-U activated at 800
o
C.
3.1.2. TGA analysis
The weight loss pattern of the samples was measured by TGA and shown in Fig. 2. TGA
thermogram of RH-AC is also included in Fig. 2 for comparison. For RH-AC, there are two
degradation steps: i) The initial weight loss below 350
o
C is ascribed the decomposition of surface
functional groups (carboxyl and lactone groups); ii) The second weight loss from 350~600
o
C
accompanied an exothermic peak at 513.53
o
C in DTA curve is attributed to the removal of more
stable functional groups (phenol, carbonyl, and quinone [8]) and the degradation of the carbon
skeleton [9]. For MnAC samples, the weitghtloss starts at about 250
o
C then drastically drop in
Synthesis, characterization and electrochemical performance
585
the range of 270-300
o
C and is accompanied by a sharp exothermic peak in DTA curve. This
weight loss is corresponded to the removal of carbon from the sample under the catalyst of
MnO2 particles [10]. The exothermic peak of MnAC-M (271
o
C) is lower than that of MnAC-U
(284
o
C), this apparently the effect of manganese oxide is higher in magnetic preparing sample.
The weight loss in the temperature range of 300 – 400 oC is probably caused by the combustion
of carbon without the presence of manganese oxide [10]. The small weight loss in the range of
400-550
o
C is attributed to the loss of oxygen from MnO2 lattice to form Mn2O3 [11]. RH-AC is
completely combusted at 550
o
C, therefore the remaining at 600
o
C can be assigned to the
manganese oxide (Mn2O3) on the activated carbon surface. The remaining of all samples and the
calculated MnO2 percentage are summarized in Table 1. It could be seen from Table 1 that the
samples prepared by magnetic stirring (40.97 %) have higher manganese oxide content than
prepared by ultrasonic stirring (34.25 %).
T (
o
C)
100 200 300 400 500 600
TGA (%)
-80
-60
-40
-20
0
20
40
60
80
100
120
DTA (uV/mg)
0
100
200
300
400
500
MnAC-M
MnAC-U
RH-AC
Figure 2. TGA thermograms of RH-AC and MnAC samples.
Table 1. Weight of the remaining at 600
o
C and the calculated metal percentages.
Sample
% remaining
weight at 600
o
C
% MnO2
RH-AC 0.0 0.0
MnAC-M 37.2 40.97
MnAC-U 31.1 34.25
3.1.3. TPR-H2 analysis
The TPR-H2 characterization of MnAC samples and RH-AC are reported in Fig. 3. RH-AC
is stable up to 500
o
C and the small peak at 550
o
C is attributed to the methanation of carbon (C
+ H2 → CH4) [12]. All the MnAC samples show three well-distinct peaks, corresponding to the
reduction steps of MnO2. The first peak at 250
o
C is assigned to the reduction of MnO2 to
Luong Thi Thu Thuy, Le Van Khu, Nguyen Thi Kim Lien
586
Mn2O3. The second peak at 370
o
C is the second step of reduction from Mn2O3 to Mn3O4, and
the third peak at 440
o
C is attributed to the reduction of Mn3O4 to MnO [13].
Temperature (°C)
100 200 300 400 500 600
T
C
D
S
ig
n
a
l
(a
.u
.g
-1
)
RH-AC
MnAC-M
MnAC-U
Figure 3. TPR-H2 profile of RH-AC.
MnAC-M
Temperature (°C)
150 200 250 300 350 400 450 500 550 600
T
C
D
C
o
n
c
e
n
tr
a
ti
o
n
10.1
10.2
10.3
10.4
10.5
10.6
515
373
425
237
204
MnAC-U
Temperature (°C)
150 200 250 300 350 400 450 500 550 600
T
C
D
C
o
n
c
e
n
tr
a
ti
o
n
10.1
10.2
10.3
10.4
10.5
10.6
10.7
527
374
444
254
250
Figure 4. Deconvolution of TPR-H2 profile of MnAC samples.
Table 2. H2 consumption of MnAC samples.
Sample Total H2 consumption
(mmol g
-1
)
MnO2
(%)
MnAC-M 4.8513 42.18
MnAC-U 3.7607 32.69
It is worthy to mention that the first peak appeared earlier than the reduction temperature of
α-MnO2 or γ-MnO2 (307~330
o
C) [14], this might be because MnO2 is in amorphous state and
have good dispersion on the surface of activated carbon. Percentage of MnO2 can be calculated
after peak deconvolution (Fig. 4) with the assumption that the peak after 500
o
C is the methanation of
carbon and the last product is MnO (reduction sequence MnO2 → Mn2O3 → Mn3O4 → MnO).
Synthesis, characterization and electrochemical performance
587
Total H2 consumption and the calculated %MnO2 are listed in Table 2. It can be seen that the
manganese oxide content is higher when prepared by magnetic stirring and in good agreement with
the results from TGA analysis. The variation in MnO2 content might be explained by the different
promoting effect of stirring method to the interaction between
4MnO and C as well as the
removal of the products 2
3CO and 3HCO out of reaction zone. The magnetic stirring might
promote the interaction between
4MnO and C, which in turn increase the percentage of MnO2 in
the products compared to ultrasonic stirring.
3.1.4. SEM observation
Morphology of RH-AC and MnAC samples prepared using different stirring methods was
analyzed using SEM and the images are shown in Fig. 5. RH-AC exists in the form of spherical
shaped particles with diameter of 100 nm. Some of the particles are accumulated to form bigger
size pieces. All MnAC samples show relatively rough morphology and bear numerous pores on
the surface, which provide sufficient accessible space for electrolyte penetration. MnAC-M have
small granules and more even surface, whereas MnAC-U have mixed spherical and rod-like
particles with length of 400-500 nm, which caused by different stirring methods.
RH-AC
MnAC-M
MnAC-U
Figure 5. SEM images.
3.1.5. Nitrogen adsorption
The nitrogen adsorption – desorption isotherms of MnAC samples are shown in Fig. 6. All
the samples display a typical type I adsorption – desorption isotherm with a small hysteresis loop
characteristic of mixed microporous and mesoporous materials [15]. Physical properties of
Luong Thi Thu Thuy, Le Van Khu, Nguyen Thi Kim Lien
588
MnAC samples obtained from N2 adsorption – desorption are summarized in Table 3. From
Table 3, we can see that:
i) As compared to the precursor RH-AC, specific surface area and total pore volume of
MnAC samples are much smaller.
ii) Specific surface area and total pore volume of MnAC-M (744 m
2
g
-1
and 0.5065 cm
3
g
-1
)
are less than that of MnAC-U (832 m
2
g
-1
and 0.5809 cm
3
g
-1
). The difference in specific surface
area is due to the variation in micropore surface area (610 m
2
g
-1
compared to 692 m
2
g
-1
).
Meanwhile, the difference in pore volume is owing to the co-contribution of micropore volume
and mesopore volume (0.3428 and 0.1637 cm
3
g
-1
compared to 0.3832 and 0.1977 cm
3
g
-1
).
iii) The percentage of mesopore is higher in MnAC-U sample (34.0 % in comparison with
32.3 % of MnAC-M).
Relative Pressure (p/p°)
0.0 0.2 0.4 0.6 0.8 1.0
Q
u
a
n
ti
ty
A
d
s
o
rb
e
d
(
c
m
³/
g
S
T
P
)
0
50
100
150
200
250
300
350
MnAC-M
MnAC-U
Figure 6. Nitrogen adsorption – desorption isotherms of MnAC samples.
Table 3. Surface area and pore characteristic of MnAC samples.
Sample
SBET
m
2
g
-1
Smic
m
2
g
-1
Sext
m
2
g
-1
Vmic
cm
3
g
-1
VBJH
cm
3
g
-1
Vtot cm
3
g
-1
VBJH/Vtot %
MnAC-M 744 610 134 0.3428 0.1637 0.5065 32.3
MnAC-U 832 692 140 0.3832 0.1977 0.5809 34.0
SBET: The specific surface area, calculated by applying the BET equation to the adsorption data [16]
Smic, Sext and Vmic: The micropore surface area, the external surface area and the micropore volume,
evaluated by the t-plot method [17].
VBJH: The mesopore volume, estimated by the Barrett–Joyner–Halenda (BJH) method [18].
Vtot: The total pore volume, evaluated by the sum of micropore and mesopore volumes.
The decrease in specific surface area and pore volume is attributed to the presence of
MnO2, which has lesser specific surface area and fewer pores than RH-AC. MnAC-M has higher
MnO2 content than that of MnAC-U, therefore has smaller specific surface area as well as total
pore volume.
Synthesis, characterization and electrochemical performance
589
3.2. Electrochemical properties
3.2.1. Cyclic voltammetry
Cyclic voltammograms recorded between -1.1 and -0.1 V (vs. SCE) in 6 M KOH
electrolyte at a scan rate of 5 mV s
-1
for MnAC-M, MnAC-U, and RH-AC electrodes as well as
nickel foam (for comparison) are shown in Fig. 7. No peaks are observed in the case of bare
nickel foam, indicating that the nickel foam collector exhibits no electrochemical activity in the
investigated potential windows. Rectangular shape is observed for RH-AC electrode indicating
EDLC capacitive behavior of the material. For MnAC-M and MnAC-U in the range of -1.1 ~ -
0.7 V, the CV curves still keep the ideal rectangular shape similar to RH-AC’s which can be
ascribed to the contribution of activated carbon. Even though specific surface area of MnACs is
much smaller than that of RH-AC (744 and 832 m
2
g
-1
compared to 2990 m
2
g
-1
), the external
surface area of MnACs is slightly different (134 and 140 m
2
g
-1
, in comparison with 243 m
2
g
-1
).
During scanning, due to diffusion limitation, the solvated K
+
ions only adsorb/desorb onto
mesopore and a minority of micropores, therefore, the decrease in micropores of MnAC did not
significantly affect its electrochemical behavior and caused only slightly changed in the shape of
CV curves. In the range of -0.7 ~ -0.1 V, MnAC electrodes exhibit an integrated area notably
larger than that of RH-AC electrode and display a pair of redox reaction peaks corresponds to
the reactions MnO2 + H2O + e
-
MnOOH + OH
-
[19]. Evidently, the integrated area of
MnAC electrodes is enhanced by the combination of pseudo-capacitance and electric double
layer capacitance. This increase is possibly attributed to the contribution of MnO2. MnAC-M has
higher MnO2 content (as pointed out in TGA and TPR-H2 results), therefore, has a larger
integrated area.
v = 5 mV s
-1
E vs SCE (V)
-1.2 -1.0 -0.8 -0.6 -0.4 -0.2 0.0
i
(A
g
-1
)
-7.0
-5.0
-3.0
-1.0
1.0
3.0
5.0
7.0
MnAC-M
MnAC-U
RH-AC
Nickel-Foam
Figure 7. CV of RH-AC and MnAC electrodes in 6M KOH electrolyte at scan rate of 5 mV s
-1
.
Figure 8 presents the cyclic voltammograms of MnAC-M and MnAC-U electrodes in 6M
KOH electrolyte at scan rate from 5 to 50 mV s
-1
. Peak current increases with the increasing in
scan rate. The position of the redox peak shifts slightly at low scan rate and the peak disappeared
at scan rate higher than 30 mV s
-1
, which demonstrates diffusion-controlled kinetic [20].
Luong Thi Thu Thuy, Le Van Khu, Nguyen Thi Kim Lien
590
MnAC-M
E vs SCE (V)
-1.2 -1.0 -0.8 -0.6 -0.4 -0.2 0.0
i
(A
g
-1
)
-9.0
-6.0
-3.0
0.0
3.0
6.0
9.0
5 mV s
-1
10 mV s
-1
30 mV s
-1
50 mV s
-1
MnAC-U
E vs SCE (V)
-1.2 -1.0 -0.8 -0.6 -0.4 -0.2 0.0
i
(A
g
-1
)
-9.0
-6.0
-3.0
0.0
3.0
6.0
9.0
5 mV s
-1
10 mV s
-1
30 mV s
-1
50 mV s
-1
Figure 8. CV curves of MnAC-M and MnAC-U electrodes at different scan rates.
The specific capacitances C (F g
-1
) were calculated using equation:
I Δt
C =
2mΔV
where
I Δt is the area of the current (A) against time (s), m is the mass (g) of active material in the
electrode. The specific capacitances of all samples at different scan rates are summarized in
Table 4. It can be seen from Table 4 that:
i) The specific capacitance of all samples decreases with the increasing of scan rate,
specific capacitance of MnAC-M and MnAC-U at scan rate of 5 and 50 mV s
-1
is 338, 320 F g
-1
and 98, 100 F g
-1
, respectively. This drop off is due to the decrease in redox reaction rate of
MnO2 and in diffusion rate of K
+
ion at high scan rate.
ii) At low scan rate ( 30 mV s
-1
), specific capacitance of MnAC-M is higher than that of
MnAC-U. This might be due to the high MnO2 content of MnAC-M sample.
iii) At higher scan rate (50 mV s
-1
), MnAC-U has better electrochemical behavior, specific
capacitance is 100 and 98 F g
-1
for MnAC-U and MnAC-M, respectively. This result might be
explained by the porous structure of MnAC-U. MnAC-U has larger specific surface area and
higher mesopore volume (832 m
2
g
-1
and 0.1977 cm
3
g
-1
) as compared to that of MnAC-M (744
m
2
g
-1
and 0.1637 cm
3
g
-1
), which is more preferable for K
+
ion to access and resulted in higher
specific capacitance.
Table 4. Specific capacitance of the as prepared electrodes.
Sample
C (F g
-1
)
5 mV s
-1
10 mV s
-1
30 mV s
-1
50 mV s
-1
MnAC-M 338 190 119 98
MnAC-U 320 169 116 100
3.2.2. Charge/discharge test
Synthesis, characterization and electrochemical performance
591
To further explore the potential application as electrochemical capacitor, charge/discharge
experiments were carried out for MnAC-M and MnAC-U electrodes at current density from 0.5
to 3.0 A g
-1
over a potential window of -1.1 to -0.1 V.
i = 0.5 A g
-1
t (s)
0 300 600 900 1200 1500 1800
E
v
s
S
C
E
(
V
)
-1.2
-1.0
-0.8
-0.6
-0.4
-0.2
0.0
MnAC-M
MnAC-U
i = 2.0 A g
-1
t (s)
0 20 40 60 80 100 120 140
E
v
s
S
C
E
(
V
)
-1.2
-1.0
-0.8
-0.6
-0.4
-0.2
0.0
MnAC-M
MnAC-U
Figure 9. Galvanostatic charge-discharge curves of MnAC-M and MnAC-U at current densities of
0.5 and 2.0 A g
-1
.
i (A g
-1
)
0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5
C
(
F
g
-1
)
0
100
200
300
400
500
MnAC-M
MnAC-U
Figure 10. Specific capacitance of MnAC-M and MnAC-U at different current densities.
Figure 9 shows the representative results at current densities 0.5 and 2.0 A g
-1
. The voltage
drops are found to be rather small, indicating the low internal resistance of the electrodes. For
current density 0.5 A g
-1
, the symmetric linear straight lines represent the electric double layer
and reversible nature of the electrodes. The short horizontal lines at about -0.2 ~ -0.4 V in the
charge/discharge profile are also observed which feature the pseudocapacitive characteristic of
the samples [21]. Charge-discharge profiles indicate both the behavior of electric double layer
and pseudo-capacitance of the electrodes. For current density 2.0 A g
-1
, the horizontal lines
disappeared, indicating the distribution of EDLC is dominated at high current density, which is
agreed well with CV results.
The specific capacitance C (F g
-1
) is calculated according to the formula:
Luong Thi Thu Thuy, Le Van Khu, Nguyen Thi Kim Lien
592
IΔt
C =
mΔV
where I is the discharge current (A), Δt is the discharge time (s), m is the mass (g) of the active
material, ΔV is the discharge potential range (V). The specific capacitances calculated are
illustrated in Fig. 10. The specific capacitances gradually decrease with the increasing of the
discharging current density. The specific capacitance of MnAC-M is higher than that of MnAC-
U at low current densities and is lower than that of MnAC-U at high current densities. At current
density 0.5 A g
-1
, specific capacitance of MnAC-M and MnAC-U is 417 and 342 F g
-1
,
respectively. However, at current density 3.0 A g
-1
, the situation is reversed, 111 F g
-1
for
MnAC-U and only 105 F g
-1
for MnAC-M. This can be explained due to the contribution of
MnO2 is dominated at low current density and the contribution of EDLC is overpowered at high
current density as showed in Fig. 9.
4. CONCLUSIONS
The MnAC samples were successfully prepared via magnetic stirring and ultrasonic stirring
methods. The resulted samples are amorphous structure with 32~42% MnO2 loading. The
magnetic stirring prepared sample has spherical particles while ultrasonic stirring sample has
mixed spherical and rod-like particle. The introducing of manganese oxide resulted in a drop in
specific surface area and pore volume compared to activated carbon sample. Electrochemical
investigates show that at low scan rate or low current density, MnAC-U have better performance
while at high scan rate or high current density, MnAC-M is superior to MnAC-U.
Acknowledgements: This research has received funding from the Vietnam Ministry of Education and
Training under grant number B2016-SPH-20.
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